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Find the setting that controls which devices the system boots from. This is usually labeled as the "Boot Order" and commonly shown as a list of devices, such as Floppy, CD-ROM, First Hard Disk, and so on.
Make sure that CD-ROM is selected as a first priority boot device. Make the change, then save and exit. (In case of doubt, you should consult the manual that came with your computer, and/or its motherboard.) The computer should now restart.
Some computers have option to boot once from CD-ROM/HDD/Floppy/USB device. Keep tapping the F8 button at boot time and then choose to boot from CD-ROM when boot menu comes up.